期刊
SEPARATION AND PURIFICATION TECHNOLOGY
卷 212, 期 -, 页码 747-756出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.seppur.2018.11.062
关键词
Palladium; Solvent extraction; Biogenic sulphide; Sulphate reducing bacteria; Nanoparticles
资金
- European commission
- FCT Foundation for Science and Technology [29251]
- Algarve's Regional Operational Program (CRESC Algarve 2020) through Portugal 2020
- European Regional Development Fund (FEDER)
- FCT [UID/MULTI/04326/2013, UID/MULTI/00612/2013]
- Fundação para a Ciência e a Tecnologia [UID/Multi/00612/2013] Funding Source: FCT
Platinum group metals (PGMs) are highly demanding metals in current high-techs. However, their supply is limited due to their scarcity in natural resources and expensive mining. Solvent extraction in combination with microbial communities were employed for the recovery of palladium from aqueous media. Accordingly, extraction of Pd(II) by N,N'-dimethyl-N,N'-dicyclohexylthiodiglycolamide (DMDCHTDGA) in toluene and subsequent stripping by acidic thiourea were carried out, followed by bio-recovery employing biogenic sulphide generated from sulphate-reducing bacteria. The results revealed an excellent extraction performance of DMD-CHTDGA towards Pd(II) from metal complex mixtures in 2,4 and 6 M HCl. However, Fe(III) was co-extracted from 4 and 6 M HCl, being completely removed with deionized water during scrubbing. 94-99% of extracted Pd (II) were stripped using acidic thiourea. Over 99% of stripped Pd(II) were recovered using two solutions containing biogenic sulphide: an effluent from a bioremediation process of acid mine drainage treatment, and a supernatant solution from Postgate B nutrient medium. 78-99% of scrubbed Fe(III) were bio-recovered. Analysis of all the precipitates collected during palladium bio-recovery showed that they were composed by Pd and S, which is consistent with the synthesis of nanosized PdS. The elemental analysis of the iron precipitate also suggests the presence of iron sulphide. Henceforth, the method engaged is environmentally sustainable, safe and cheap, thus attractive to be employed, to separate and recover both Pd and Fe from waste materials.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据