期刊
POLYMER TESTING
卷 75, 期 -, 页码 337-343出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymertesting.2019.02.024
关键词
Nitrocellulose; Isothermal decomposition; Mechanism
资金
- Science Challenge Project [TZ2018004]
- Natural Science Foundation of China [21875192, 11602240]
- Key Projects of the Pre-research Fund of the General Armament Department [6140720020101]
- National Defense Technology Foundation Project [JSJL2016404B002]
- Institute of Chemical Materials, China Academy of Engineering Physics [18zh0079]
Nitrocellulose (NC) was investigated via an improved isothermal decomposition dynamics research instrument at temperature intervals from 378.15 to 398.15 K. Arrhenius equation and model-fitting method were used to calculate the thermal decomposition kinetic parameters. Results of these approaches were consistent, with an average E-a of 144.7 kJ mol(-1) and lnA of 27.39. The storage life of NC was estimated using the Berthelot equation. Results showed that the effective storage life of NC at ambient temperature (298.15 K) was extrapolated to 10.57 years with the extent of reaction reaching 0.1% and 52.91 years with the extent of reaction reaching 0.5%. The thermodecomposition gas and residues of NC were verified by GC, FT-IR, and SEM. The possible reaction mechanism of the isothermal decomposition of NC was provided.
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