期刊
POLYMER
卷 168, 期 -, 页码 246-254出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2019.02.054
关键词
PVDF; P(VDF-TrFE-CTFE); P(VDF-HFP); Polymer blends; Energy storage; Polar nanostructure
资金
- Engineering and Physical Sciences Research Council [EP/L017695/1]
- China Scholarship Council (CSC) [201606280030]
- EPSRC [EP/L017695/1] Funding Source: UKRI
Flexible polymer-based dielectric capacitors with superior power density and stability are irreplaceable components in modern electrical devices. Among all dielectrics, ferroelectric relaxor materials are the most competitive candidates due to their high discharged energy density U(e )and efficiency arising from their reversible polar nanodomains at high electric field. Poly(vinylidenedifluoride - trifluoroethylene - chlorotrifluoroethylene) (P(VDF-TrFE-CTFE)), one of the most well-known ferroelectric relaxor polymers, suffers from some limitations, including, poor processability, relatively low breakdown strength and high cost, which inhibit its potential commercial use. In this work, these restrictions have been effectively addressed via a low-cost binary polymer blending route. Owing to the high compatibility and strong interactions between P(VDF-TrFE-CTFE) and Poly (vinylidene difluoride-hexafluoropropylene) (P(VDF-HFP)), the nanostructure of blends can be modulated, which significantly enhanced the reversible polarization Pin-max to 0.132 C/m(2) at the breakdown strength Eb of 600 kV/mm, leading to a high energy density of 21.9 J/cm(3 )in oriented P(VDF-TrFE-CTFE)/P(VDF-HFP) (50/ 50 wt %) blended films. The simplicity of the blending approach and the industrial viability of the processing technique, melt-extrusion, combined with high discharged energy density make oriented P(VDF-TrFE-CTFE)/P (VDF-HFP) (50/50 wt %) blended films a potential candidate for advanced energy storage applications.
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