期刊
PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION
卷 36, 期 7, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ppsc.201900090
关键词
cobalt phosphosulfide; electrocatalyst; graphene oxide; hydrogen evolution reaction; nanoparticle
资金
- National Research Foundation of Korea (NRF) - Ministry of Science, ICT, and Future Planning [NRF-2016M3A7B4905613]
Efficient water electrolysis catalyst is highly demanded for the production of hydrogen as a sustainable energy fuel. It is reported that cobalt derived nanoparticle (CoS2, CoP, CoS|P) decorated reduced graphene oxide (rGO) composite aerogel catalysts for highly active and reliable hydrogen evolution reaction electrocatalysts. 7 nm level cobalt derived nanoparticles are synthesized over graphene aerogel surfaces with excellent surface coverage and maximal expose of active sites. CoS|P/rGO hybrid aerogel composites show an excellent catalytic activity with overpotential of approximate to 169 mV at a current density of approximate to 10 mA cm(-2). Accordingly, efficient charge transfer is attained with Tafel slope of approximate to 52 mV dec(-1) and a charge transfer resistance (R-ct) of approximate to 12 omega. This work suggests a viable route toward ultrasmall, uniform nanoparticles decorated graphene surfaces with well-controlled chemical compositions, which can be generally useful for various applications commonly requiring large exposure of active surface area as well as robust interparticle charger transfer.
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