期刊
ORGANOMETALLICS
卷 38, 期 20, 页码 3906-3911出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.9b00067
关键词
-
资金
- National Key R&D Program of China [2016YFA0202900, 2015CB856600]
- National Natural Science Foundation of China [21825109, 21821002, 21732006, 21572255, 21432011]
- Chinese Academy of Sciences [XDB20000000, QYZDB-SSW-SLH016]
- Science and Technology Commission of Shanghai Municipality [17JC1401200]
The asymmetric hydrogenation of vinylsilanes catalyzed by a new C-1-symmetric phosphine-pyridine-oxazoline cobalt complex is described. The method provides an efficient approach to chiral tertiary silanes with enantioselectivities up to 99% ee. Furthermore, the o-methylsubstituted benzylic silane products undergo ruthenium-catalyzed dehydrogenative silylation to produce chiral benzosilolanes in high yields without racemization of the stereogenic center alpha to the quaternary Si atom.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据