期刊
ORGANIC LETTERS
卷 21, 期 11, 页码 4327-4330出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01501
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资金
- CSC (China Scholarship Council)
A new gold-catalyzed C-H annulation of sulfilimines with N-phenylynamides is presented. As key intermediates of this operationally simple reaction, the in situ generated a-imino gold carbenes insert into the ortho C-H bonds of the phenyl groups to afford 2-aminoindoles bearing a variety of substitution patterns in high selectivities. This reaction offers a facile approach to biologically important 2-aminoindoles by using inexpensive and readily available starting materials.
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