期刊
ORGANIC LETTERS
卷 21, 期 11, 页码 4318-4321出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01490
关键词
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资金
- Universite libre de Bruxelles (ULB)
- FNRS [PDR T.0160.18]
- Fonds pour la formation a la Recherche dans l'Industrie et dans l'Agriculture (F.R.I.A.)
An efficient total synthesis of the chlorinated thiazole-containing natural product conulothiazole A is reported. Key features of this synthesis include a novel rhodium-catalyzed enantioselective hydrogenation of a 2-enamido-thiazole and a vinylic Finkelstein reaction that could be implemented at all stages of the synthesis to install the chlorinated alkene.
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