期刊
ORGANIC LETTERS
卷 21, 期 10, 页码 3653-3657出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01092
关键词
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资金
- Dean's Seed Fund of RWTH Aachen University
- Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) [408033718]
The rearrangement of selenium ylides is even today almost unexplored, although it would provide access to important organoselenium compounds with broad downstream applications. In this report, the first systematic study of sigmatropic rearrangement reactions of selenium ylides using a simple rhodium catalyst with catalyst loadings as low as 0.01 mol % is described. Selenium oxide pyrolysis of the rearrangement products gives access to important 1,1-disubstituted butadienes.
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