期刊
ORGANIC LETTERS
卷 21, 期 11, 页码 4082-4086出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01263
关键词
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资金
- NSFC [21202040, 21603062, 21572047]
- China Postdoctoral Science Foundation [2014M552007, 2015T80771]
- Plan for Scientific Innovation Talents of Henan Province [184200510012]
- 111 Project [D17007]
Rh(III)-catalyzed site-selective oxidative spirocyclization reactions of isoquinolones with alpha-diazo-1,3-indandiones leading to three kinds of Spiro compounds by employing isoquinolones with different structural features or tuning the reaction parameters are presented. In addition, a plausible catalytic cycle is proposed on the basis of control experimental results and density functional theory calculations. Finally, the diverse transformations of the spiro products into other complex skeletons demonstrate the synthetic utility of this protocol.
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