期刊
ORGANIC LETTERS
卷 21, 期 9, 页码 3183-3186出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00897
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资金
- European Union (European Social Fund - ESF)
- Greek national funds through the Operational Program Education and Lifelong Learning of the National Strategic Reference Framework (NSRF) - Research Funding Program: Heracleitus II [346942-PiE1.93]
- National Strategic Reference Framework (NSRF) - Research Funding Program
- ESF [11SigmaYN-3-770]
Vagiallene (1), a rearranged C-15 acetogenin with a molecular formula and a carbon skeleton unprecedented in natural products, was isolated as a trace constituent from the organic extract of the red alga Laurencia obtusa from Lefkada island. The planar structure and the relative configuration of 1 were established on the basis of extensive analysis of its spectroscopic data, while its absolute configuration was determined by comparison of its experimental and quantum-mechanically predicted electronic circular dichroism spectra.
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