期刊
ORGANIC LETTERS
卷 21, 期 9, 页码 3377-3381出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01116
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资金
- University of Chicago
A direct beta-alkenylation of simple ketones with alkenyl bromides is reported via a Pd-catalyzed redox cascade strategy. The reaction is redox neutral and directing-group-free, in the absence of strong acids or bases. Both cyclic and linear ketones are suitable substrates, and various alkenyl bromides can be coupled. The resulting beta-alkenyl ketones are readily derivatized through diverse alkene functionalization.
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