期刊
ORGANIC LETTERS
卷 21, 期 8, 页码 2750-2754出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00701
关键词
-
资金
- National Natural Science Foundation of China [21702230]
- Natural Science Foundation of Jiangsu Province [BK20160743]
- Program for Jiangsu Province Innovative Research Team, Double First-Class Project of China Pharmaceutical University [CPU2018GY35, CPU2018GF05]
- 111 Project [B16046]
Manganese-photocatalyzed activation of the Si H bond in silanes for the hydrosilylation of alkynes has been developed. The mild protocol operates efficiently with high regioselectivity (anti-Markovnikov) and stereoselectivity (Z/E ratio ranges from 92:8 to >99:1), providing a wide range of Z-vinylsilanes in high yields. Moreover, visible-light-induced manganese-catalyzed activation of the Ge-H bond for E-selective alkyne hydrogermylation is reported for the first time.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据