期刊
NANO RESEARCH
卷 12, 期 5, 页码 1193-1197出版社
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-019-2381-0
关键词
Ni-rich phosphides; carbon nanotube; high conductivity; catalytic effect; lithium sulfur battery
类别
资金
- National Natural Science Foundation of China [21776041, 21875028]
- Cheung Kong Scholars Programme of China [T2015036]
Lithium sulfur battery has been identified as a promising candidate for next storage devices attributing to ultrahigh energy density. However, non-conductive nature of sulfur and shuttling effect of soluble lithium polysulfides are intractable remaining problems. Herein, we develop a highly conductive nickel-rich Ni12P5/CNTs hybrid with high specific surface area as sulfur host to address these issues. The polar nature of Ni12P5/CNTs can significantly relieve the shuttle effect by means of a strong affinity towards lithium polysulfides and enhance kinetics of polysulfides redox reactions. In addition, the Ni12P5/CNTs with a superior conductivity (500 Sm-1) and high surface area of 395 m(2)g(-1) enables the effective electron transfer and expedited interfacial reaction. As a result, Ni12P5/CNTs hosted sulfur cathode exhibits high rate capability (784 mAhg(-1) at 4 C) and stable cycling performance with a negligible capacity fading of 0.057 % per cycle over 1,000 cycles at 0.5 C. This work paves an alternative way for designing high performance sulfur cathodes involved metal-rich phosphides.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据