期刊
MOLECULES
卷 24, 期 9, 页码 -出版社
MDPI
DOI: 10.3390/molecules24091644
关键词
photocatalysis; ATRA reactions; olefins; sustainable catalysis; ruthenium-based complexes
资金
- John S. Latsis Foundation
- Hellenic Foundation for Research and Innovation (ELambdaIDeltaEK)
- State Scholarships Foundation (IKY)
- National and Kapodistrian University of Athens
Photocatalysis is a rapidly evolving area of research in modern organic synthesis. Among the traditional photocatalysts, metal-complexes based on ruthenium or iridium are the most common. Herein, we present the synthesis of two photoactive, ruthenium-based complexes bearing pyridine-quinoline or terpyridine ligands with extended aromatic conjugation. Our complexes were utilized in the atom transfer radical addition (ATRA) of haloalkanes to olefins, using bromoacetonitrile or bromotrichloromethane as the source of the alkyl group. The tailor-made ruthenium-based catalyst bearing the pyridine-quinoline bidentate ligand proved to be the best-performing photocatalyst, among a range of metal complexes and organocatalysts, efficiently catalyzing both reactions. These photocatalytic atom transfer protocols can be expanded into a broad scope of olefins. In both protocols, the photocatalytic reactions led to products in good to excellent isolated yields.
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