期刊
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
卷 138, 期 6, 页码 3997-4001出版社
SPRINGER
DOI: 10.1007/s10973-019-08388-1
关键词
Triazole phenyltriazole; Water calorimetry; Enthalpy heat capacity
资金
- Russian Science Foundation [18-73-00217] Funding Source: Russian Science Foundation
This paper focuses on the thermochemical behavior of two derivatives of 1,2,4-triazole which is often considered as a potential synthetic platform to develop novel antitumor or antimicrobial drugs, i.e., 3,5-diamino-1,2,4-triazole (compound 1) and 3,5-diamino-1-phenyl-1,2,4-triazole (compound 2). Experimental enthalpies of solution in water have been determined calorimetrically over the physiological temperature range. These quantities are used to compute standard enthalpies and heat capacities of solution. Standard partial molal heat capacities of solution are calculated from the heat capacities of solution and experimentally determined heat capacities of solid heterocycles. The results obtained are compared with those for hydrophilic urea and hydrophobic benzene and briefly discussed.
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