期刊
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
卷 97, 期 -, 页码 105-111出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jtice.2019.02.024
关键词
Alkali metal salts; Acid; Corn stover; Furans; H2O-THF co-solvent system
资金
- National Natural Science Foundation of China [51476180]
The preparation of furans from catalytic conversion of corn stover is investigated in H2O-THF (tetrahydrofuran) co-solvent system, and the effects of Bronsted acids (H2SO4, HCl, HNO3) combined with alkali metal cations (Li+, Na+,K+) are studied systematically. It is found that the effect of individual acid in promoting the summary yield of 5-hydroxymethylfurfural (HMF) and furfural (FF) can be ordered as CI- > SO42- > NO3-. When combined with a salt, the anion effect can be ranked in SO42- > Cl - > NO3, both for the HMF yield and the summary yield of furans. Based on the best anion of SO42-, the impacts of the combined cations can be finely ranked as Na+ > K+ > Li+. For the system with Cl-, it ranks in K+ > Li+ > Na+ for the HMF yield or the summary yield of furans. The performance of NO3- is so poor that no liquid product can be detected when any alkali metal cations is combined with HNO3. The performance of H2SO4/Na2SO4 is the best among 9 tested combined catalysts, and the yield of HMF and FF from corn stover conversion under optimized conditions are 76% and 81% respectively. (C) 2019 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
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