期刊
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 39, 期 14, 页码 4338-4346出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2019.05.050
关键词
Zirconia; Phase transformation; Rare earth oxide; Co-stabilized; Nano-powder
资金
- National Key R&D Program of China [2017YFB0305700]
- Major Special Project for Industry-university-research Collaborative Innovation of Guangzhou City [201604020139]
- Project for Science and Technology Program of Guangdong Province [2016A020220005]
- Major Special Projects for Science and Technology Program of Guangdong Province [20148010129002, 2016B090913001]
Yttria, yttria-ceria and yttria-ceria-lanthana stabilized zirconia powders were prepared by coprecipitation. Their tetragonal-to-monoclinic phase (t -> m) transformation was investigated by calcining the powders in a temperature range of 400-1400 degrees C for 2 h. The results show that after doping with 0.1 to 0.3 mol.% La2O3 and calcining at 1400 degrees C in air, unusual redox behaviours of cerium were detected in the 1.5 mol.% Y2O3+5.5 mol.% CeO2 co-stabilized zirconia. Grain refinement and a sharp reduction in oxygen vacancy concentration were observed simultaneously. The t -> m transition was not found in the 0.1 mol.% La2O3 doped zirconia but appeared in the cases with a higher dopant content. The changes are discussed with regards to the grain size, valence change of cerium, presence of oxygen vacancies, and segregation of the dopants at grain boundaries.
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