期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 23, 页码 9129-9133出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b00941
关键词
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资金
- European Research Council [692981]
- Ministero dell'Istruzione, University e Ricerca (FARE grant) [R16S9XXKX3]
- European Research Council (ERC) [692981] Funding Source: European Research Council (ERC)
We exploit a reversible acid base triggered molecular shuttling process to switch an appropriately designed rotaxane between prochiral and mechanically planar chiral forms. The mechanically planar enantiomers and their interconversion, arising from ring shuttling, have been characterized by NMR spectroscopy. We also show that the supramolecular interaction of the positively charged rotaxane with optically active anions causes an imbalance in the population of the two enantiomeric coconformations. This result represents an unprecedented example of chiral molecular recognition and can disclose innovative approaches to enantioselective sensing and catalysis.
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