期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 17, 页码 6822-6826出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b02375
关键词
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资金
- National Science Foundation of China [21471062, 21671172]
- Center for Gas Separations Relevant to Clean Energy Technologies, an Energy Frontier Research Center (EFRC) - U.S. Department of Energy (DOE), Office of Science, and Office of Basic Energy Sciences [DESC0001015]
- Office of Fossil Energy
- National Energy Technology Laboratory [DE-FE0026472]
- Robert A. Welch Foundation through a Welch Endowed Chair [A-0030]
Due to the structural advantages displayed by Metal-Organic Frameworks (MOFs), integrating Valence Tautomerism (VT) systems within MOFs could be an effective strategy in order to break through the constraints of the traditional ones. Herein, we report the first successful integration of a VT system into a MOF termed VT-MOF-1. The structural characteristics of VTMOF-1, such as dinuclear cobalt-catechol clusters and solvent-accessible pores, are both innovative and novel, potentially yielding new vitality within VT field. In addition, VT-MOF-1 exhibits specific behaviors responsive to temperature and different solvent molecules as nbutanol, tert-butanol, and isopropyl alcohol. The entropy values and configurations of the solvent molecules might be responsible for the tunable sensing behaviors.
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