期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 15, 页码 6152-6156出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b01891
关键词
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资金
- CSIR India
- IISER-Kolkata startup grant
- DST-Swarna Jayanti Fellowship grant [DST/SJF/CSA-02/2016-2017]
- SERB [EMR/2015/000030]
- HPC time on THOMAS through the Materials Chemistry Consortium [EP/L000202]
- EPSRC [EP/R029431/1] Funding Source: UKRI
Visible light-mediated photocatalytic organic transformation has drawn significant attention as an alternative process for replacing thermal reactions. Although precious metal/organic dyes based homogeneous photocatalysts have been developed, their toxic and nonreusable nature makes them inappropriate for large-scale production. Therefore, we have synthesized a triazine and a keto functionalized nonmetal based covalent organic framework (TpTt) for heterogeneous photo catalysis. As the catalyst shows significant absorption of visible light, it has been applied for the photocatalytic uphill conversion of trans-stilbene to cis-stilbene in the presence of blue light-emitting diodes with broad substrate scope via an energy transfer process.
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