期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 15, 页码 6180-6184出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b02510
关键词
-
资金
- NSERC of Canada
- Canada Research Chair
- Einstein Visiting Professorship at TU Berlin
- Alexander Graham Bell Canada Graduate Scholarship
- German Science Foundation (DFG)
Reaction of dihydrogen and the borinium cation salt [Mes(2)B][B(C6F5)(4)] gave an arene-stabilized mesityl-borenium cation, which isotopically scrambles HD. Similarly, reaction with triethylsilane gave the diboranium cation [MesB(mu-H)(2)(mu-Mes)BMes](+) featuring three bridge-bonds between two boron centers. Reaction of same (Mes(2)BH)(2) with Bronsted acid also afforded the same diboranium whereas the corresponding reaction with (MesBH(2))(2) yielded the triboron cation [H2B(mu-H)(mu-Mes)B(mu-Mes)(mu-H)BH2](+).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据