期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 22, 页码 8758-8763出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b03998
关键词
-
资金
- ETH Zurich
A palladium-catalyzed C-H iodination of unactivated alkenes is reported. A picolinamide directing group enables the regioselective functionalization of a wide array of olefins to furnish iodination products as single stereoisomers. Mechanistic investigations suggest the reversible formation of a six-membered alkenyl palladacycle intermediate through a turnover-limiting C-H activation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据