4.8 Article

Maximizing Photoresponsive Efficiency by Isolating Metal-Organic Polyhedra into Confined Nanoscaled Spaces

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 20, 页码 8221-8227

出版社

AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b01380

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资金

  1. National Natural Science Foundation of China [21722606, 21676138, 21576137]
  2. Project of Priority Academic Program Development of Jiangsu Higher Education Institutions
  3. Robert A. Welch Foundation [A-0030]
  4. National Research Foundation of Korea (NRF) - Korea government [NRF-2016R1C1B2009987, NRF-2016M2B2A9912217]
  5. National Research Foundation of Korea [2016M2B2A9912217] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Photoresponsive metal-organic polyhedra (PMOPs) have attracted expanding interests due to their modular nature with tunable functionality and variable responsive behaviors tailored conveniently by external-stimulus. However, their photoresponsive efficiency is often compromised after activation because of desorption-triggered aggregation into bulk PMOPs, which limits their utility in stimuli-responsive applications. Here, we report a case system that can overcome the aggregation problem and achieve maximized photoresponsive efficiency by polyhedral isolation in the nanoscaled spaces of mesoporous silica (MS). Through confinement, amount-controllable PMOPs are well dispersed in the nanoscaled spaces of MS, avoiding aggregation that commonly takes places in bulk PMOPs. Furthermore, reversible trans/cis isomerization of photoresponsive groups can be realized freely during ultraviolet/visible light irradiation, maximizing control over photoresponsive guest adsorption behaviors. Remarkably, after trans/cis isomerization, the confined PMOP-1 shows 48.2% of change in adsorption amount for propene with small molecular size and 43.9% for brilliant blue G (BBG) with large molecular size, which is significantly higher than that over bulk PMOP-1 with 11.2% for propene and 7.8% for BBG, respectively. Therefore, our work paves a way for the design and construction of multifunctional composite materials toward efficient stimuli-responsive needs.

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