期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 102, 期 12, 页码 7355-7365出版社
WILEY
DOI: 10.1111/jace.16602
关键词
Curie temperature; direct current resistivity; ferroelectric material; piezoelectric properties
BiFeO3-BaTiO3 ceramics are promising lead-free piezoelectric ceramics due to their high piezoelectric properties and high Curie temperature, but their high leakage current density makes the poling difficult. In this study, a decreased leakage current density by three orders of magnitude was obtained in Bi0.5Na0.5TiO3 (BNT) added 0.67BiFeO(3)-0.33BaTiO(3) (BF-BT) ceramics. It was found that the largely improved insulating properties benefit from the reduced oxygen vacancies and weak reduction of Fe3+ to Fe2+ as confirmed by photoluminescence and X-ray photoelectron spectroscopy measurements, thereby contributing to high-temperature and high-field poling. In addition, the introduction of BNT leaded to increased grain size. Due to the grown grains as well as reduced oxygen vacancies and Fe2+, enhanced insulating and optimal piezoelectric properties with P-r = 24.2 mu C/cm(2), d(33) = 183 pC/N, k(p) = 0.28, and T-C = 467 degrees C were achieved in BF-BT-0.05BNT ceramics.
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