期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 57, 期 12, 页码 1265-1269出版社
WILEY
DOI: 10.1002/pola.29386
关键词
atom transfer radical polymerization; dyes; organocatalysis; photopolymerization; polyacrylonitrile
资金
- National Natural Science Foundation of China [51773086, 51573075, 21808098]
- Key Program for Basic Research of Natural Science Foundation of Shandong Province [ZR2018ZC0946]
- Natural Science Foundation of Shandong Province [ZR2018BB027]
- Project of Shandong Province Higher Educational Science [J16LC20, J18KA080]
A visible light-induced metal-free atom transfer radical polymerization strategy for the efficient synthesis of polyacrylonitrile (PAN) with predictable molecular weights and low dispersities has been developed. High conversions can be obtained by using commercially available organic dyes as the photocatalysts under mild conditions in a living/controlled manner. Moreover, PAN can be obtained with moderate conversion under the irradiation of sunlight.
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