期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 11, 页码 6904-6915出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b00659
关键词
-
资金
- National Natural Science Foundation of China [21572110, 21372137]
Different 1,2-migrations and cyclizations of a variety of alkynylbenziodoxolones (EBXs) and amidoximes under one-base conditions are described. This process provides an efficient protocol for the divergent synthesis of two oxadiazine derivatives via switchable selectivity of EBXs controlled by simply varying the substituents of the amidoximes, which feature transition metal-free conditions, simple execution, and high chemoselectivity.
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