期刊
JOURNAL OF MEMBRANE SCIENCE
卷 577, 期 -, 页码 153-164出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.memsci.2019.01.052
关键词
Amphoteric ion-exchange membrane; Crosslinking; Mono-/bi-valent anion separation; Poly(arylene ether sulfone); Electrodialysis
资金
- National Natural Science Foundation of China [21878273]
- National Key Research and Development Plan of China [2017YFC0403701]
- 63rd China Postdoctoral Science Foundation [2018M632505]
- Project for Assistance of Qinghai from Science and Technology Department of Zhejiang Province of China [2018C26004]
Fabricating stable mono-/multi-valent anion-selective membranes with high perm-selectivity for electrodialysis (ED) applications is critical but challengeable. In this work, we have fabricated a series of novel homogeneous monovalent anion-selective amphoteric ion-exchange membranes (AIEMs, PAES-im-Xc) based on a long-side-chain type imidazolium-functionalized poly(arylene ether sulfone) cross-linked with 4,4'-diazostilbene-2,2'-disulfonic acid disodium salt (DAS) for ED. By tuning the mass percent of DAS added, low swelling ratio but appreciably high anion perm-selectivity (in Cl-/SO(4)(2-)system) of optimized AIEM are achieved to values of 8.0% and 47.12 at current density of 2.5 mA cm(-2), respectively. In particular, at an enhanced current density of 5.0 mA cm(-2), its perm-selectivity reaches 12.5, significantly outperforming commercial monovalent anion-selective Neosepta ACS (5.27). The appreciably high perm-selectivity possibly arises from pore-size sieving effect from dense matrix structure with cross-linkings and strong electrostatic repulsion between negative fixed -SO3- groups and negative divalent ions of SO42- in feeding solution. The superior performances might be particularly interesting findings that can facilitate the development of advanced mono-/bi-valent anion-selective membranes in applications of sea water desalination, resource recovery and water treatment/pretreatment etc..
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