期刊
JOURNAL OF LUMINESCENCE
卷 208, 期 -, 页码 201-207出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jlumin.2018.12.039
关键词
Sr3NaSbO6:Mn4+; Photoluminescence; Optical properties; Plant growth; Far red-emitting LED
类别
资金
- Doctoral Research Foundation of Hebei Normal University of Science and Technology [2016YB003]
- instrumental analysis center of Hebei Normal University of Science and Technology
Far red-emitting Mn4+-activated oxide phosphor based on the substitution of Mn4+ for Sb5+ in the lattice of Sr3NaSbO6 (SNSO) was prepared via solid state reaction process. The crystal structure of the host was carefully discussed and studied. The resultant phosphors were characterized by X-ray powder diffraction, fluorescence spectra, ultraviolet-visible diffuse reflectance spectra, temperature-dependent emission spectra (298-548 K), luminescence decay curves and electroluminescence spectra. Excitation and emission spectra indicated that the sample had a wide excitation band in UV(250-400 nm) and exhibited the strong emission band centered at 695 nm. The band structure for SNSO was calculated based on the density functional theory, and the bandgap value of SNSO host is similar to 2.92 eV. In addition, the mechanism of quenching concentration and energy-transfer of SNSO:Mn4+ were explored and analyzed in detail through calculation. The UV-Vis diffusion reflectance spectra demonstrated that samples had strong absorption (200-550 nm) in the ultraviolet( UV) and near-ultraviolet (NUV) region. The thermal stability of SNSO:Mn4+ was excellent (I-423K/I-273K = 39.84%). The internal quantum efficiency is 56.2%. In brief, the prepared phosphors had potential application in indoor plant growth as a LED lamp.
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