Graphene oxide/titania photocatalytic ozonation of primidone in a visible LED photoreactor

A graphene oxide-titania (GO/TiO2) composite was synthesized via sol-gel method, and studied in aqueous Primidone mineralization with ozone and LED visible light. The photocatalyst was characterized by different techniques (XRD, TEM, SBET, TGA, UV-vis diffuse reflectance spectroscopy). The band gap value decrease from 3.14 eV for bare TiO2 samples to 2.5 eV in GO/TiO2 composites clearly shows the interaction of GO with TiO2 structure. Approximately 20 mg L-1 of Primidone was removed in less than 20 min if ozone was applied, regardless of the presence or absence of light and catalyst. However, reactivity tests show a synergism effect between photocatalysis and ozonation for mineralization purposes. The combination of ozone and GO improved the activation of TiO2 under visible light. Process optimization led us to select a catalyst dosage of 0.25 g L-1, a light radiance of 359 m(-2) and a GO loading in the catalyst around 0.75%. At these conditions, with photo catalytic ozonation, the presence of GO in the catalyst improved mineralization up to 82% in 2 h compared to 70% reached with bare TiO2. Catalyst reusability shows no decrease of photocatalytic activity. Scavenger tests point to hydroxyl radicals as the main species responsible for Primidone removal.