期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 367, 期 -, 页码 224-245出版社
ELSEVIER
DOI: 10.1016/j.jhazmat.2018.12.023
关键词
Adsorption; Ion exchange; Numerical models; Kinetics; Batch systems; Analytical solutions; HSDM; Variable diffusivity
资金
- ORAU project Hyperstiochiometry Activity in Metal Nanoparticle Interaction (HYPERActiv), Nazarbayev University [SOE2015009]
- HORIZON 2020 project Nanoporous and Nanostructured Materials for Medical Applications (NanoMed), H2020-MSCA-RISE-2016, European Commission [734641]
- COST Action [CRoNoS - IC408]
Adsorption and ion exchange phenomena are encountered in several separation processes, which in turn, are of vital importance across various industries. Although the literature on adsorption kinetics modeling is rich, the majority of the models employed are empirical, based on chemical reaction kinetics or oversimplified versions of diffusion models. In this paper, the fifteen most popular simplified adsorption kinetics equations are presented and discussed. A new versatile variable-diffusivity two-phase homogeneous diffusion model is presented and used to evaluate the analytical adsorption models. Aspects of ion exchange kinetics are also addressed.
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