期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 552, 期 -, 页码 604-612出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2019.05.094
关键词
Asymmetric capacitive deionization; Two-dimensional materials; Boron-nitride-carbon; Porous structure; Surface charge
资金
- National Science Foundation of China [21878049, 21336001]
- NSFC [U1507103]
- Qinghai Province State People's Government [U1507103]
Capacitive deionization (CDI) has long been identified as a hopeful solution for adsorption of ions from saline water. Developing stable electrode materials is of great significance to the improvement of CDI performance. In this work, two kinds of boron-nitride-carbon (BCN and MBCN) materials were synthesized for capacitive deionization (CDI) application. The BCN featured with high specific surface area (1097.5 m(2) g(-1)) and positive surface charges (E-pzc of -0.445 V vs. Ag/AgCl) is a good anodic candidate in the CDI device. After configuring with activated carbon, the asymmetric CDI cell exhibits excellent salt adsorption capacity of 17.46 mg g(-1) at supplied voltage of 1.4 V when the feeding NaCl concentration is 300 mg L-1 and robust cycle performance with 81.4% capacity retention after 50 cycles at supplied voltage of 1.0 V with initial salt concentration of 500 mg L-1. Overall, in contrast to that of MBCN and carbon materials, the BCN nanosheets demonstrate a high removal capacity and superior cycling stability even at low salt concentration. The stable and positively charged BCN should be a good choice for next generation of high performance CDI electrode materials. (C) 2019 Elsevier Inc. All rights reserved.
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