期刊
JOURNAL OF CLEANER PRODUCTION
卷 215, 期 -, 页码 22-33出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2019.01.003
关键词
Biomass ash; Multistage countercurrent leaching; Response surface methodology; Potassic fertilizer; Fractional crystallization; Selective precipitation
资金
- Department of Science and Technology, Government of India [INT/SWISS/SNSF/P-54/2015]
- CSIR network project K-TEN
- CSIR-India
- Centralized Instrument Facility
Potassic fertilizer was synthesized from cotton boll ash retrieved after solar gasification at 1100 degrees C. The ash was leached through batch-wise multistage countercurrent leaching, while the parameters were optimized using Response Surface Methodology. A face-centered central composite design was employed to scrutinize the effects of four independent variables- number of leaching stages, solvent to ash ratio, leaching time and particle size while the investigated response variable was K+ leaching efficiency, defined as the ratio of extracted K+ to total available water-leachable K+ in the ash. The validated model achieved a desirability of 0.92 and identified the optimal operating leaching conditions with a predicted K+ leaching efficiency of 98.8%. For synthesis of potassic fertilizer, routes of fractional crystallization and selective precipitation (using tartaric acid) were studied; the former recovers 97% of potassium as K2SO4 and KCl whereas the latter recovers 94% as KNO3. (C) 2019 Elsevier Ltd. All rights reserved.
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