期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 782, 期 -, 页码 576-585出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2018.12.163
关键词
Spent Zn-Mn batteries; NaTi2(PO4)(3)/C; Flexible supercapacitor; Nitrogen doping
资金
- National Natural Science Foundation of China [51272143]
- Natural Science Foundation of Shandong Province [ZR2017QB003]
Spent Zn-Mn batteries (ZMBs) pose a serious threat on eco-system and human health because of the toxic heavy metal ions released from ZMBs into the environment. In this report, carbon package is recycled from spent ZMBs and used as a positive electrode material for flexible supercapacitors. In a three-electrode system using 1 mol L-1 Na2SO4 as the electrolyte, the recycled carbon package (RCP) can deliver a specific capacitance of 100 Fg(-1) at 1 Ag-1. After 5000 cycles at 1 Ag-1, a specific capacitance of 86 Fg(-1) is retained with nearly 100% coulombic efficiency. Nanocomposite of NaTi2(PO4)(3) with nitrogen-doped carbon layer (NTP/C) is prepared through a simple co-precipitation plus annealing method. NTP/C can deliver specific capacity of 320 and 273 Fg(-1) at 1 and 10 Ag-1, using 1 mol L-1 Na2SO4 as the electrolyte. The high rate capability of NTP/C is attributed to the high specific surface area and nitrogen-doped carbon layer. Flexible asymmetric supercapacitors are assembled in configuration of NTP/C parallel to RCP, using 1 mol L-1 Na2SO4 as the electrolyte and stainless steel foil as the current collector. At 0.5 Ag-1, the typical flexible supercapacitor cell can deliver a specific energy of 17.8 W h kg(-1) with corresponding specific power of 503 W kg(-1), and retain 15 W h kg(-1) after 2000 cycles. (C) 2018 Elsevier B.V. All rights reserved.
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