期刊
INORGANIC CHEMISTRY
卷 58, 期 9, 页码 5725-5732出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b00088
关键词
-
资金
- National Natural Science Foundation of China [21808201, 21878229, 21536001, 21606007, 21476270, 21776259]
- National Key Projects for Fundamental Research and Development of China [2016YFB0600901]
- Science and Technology Plans of Tianjin [17PTSYJC00040, 18PTSYJC00180]
Metal-organic frameworks (MOFs) are a class of advanced porous crystalline materials. However, numerous MOFs have poor chemical stability, significantly restricting their industrial application. The introduction of trifluoromethyl groups around clusters of MOFs results in a shielding effect caused by their hydrophobicity and bulkiness, thus preventing guest molecules from attacking the coordination bonds. To prove such a shielding effect, the position of the trifluoromethyl groups is rationally adjusted, with trifluoromethyl groups at the ortho positions of carboxyl groups significantly improving the chemical stability of UiO-67. The prepared UiO-67-o-2CF(3) remains intact after treatment with boiling water, 8 M HCl, 10 mM NaOH, and 50 ppm of NaF aqueous solutions. As the control experiment, trifluoromethyl groups at the meta positions of carboxyl groups have no shielding effect; hence, UiO-67-m-2CF(3 )has a stability that is lower than that of UiO-67-o-2CF(3). In addition, the shielding effect is also applied to other MOFs, including DUT-5-o-2CF(3) and Al-TPDC-o-2CF(3), confirming the universality of this strategy.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据