期刊
INORGANIC CHEMISTRY
卷 58, 期 9, 页码 5410-5413出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b00550
关键词
-
资金
- National Natural Science Foundation of China [21701091, 21761132009, 21622607]
- Open Project of the State Key Laboratory of Physical Chemistry of the Solid Surface (Xiamen University) [201707]
- K. C. Wong Magna Fund in Ningbo University
To develop efficient adsorbent materials for C2Hx, separation from methane, herein, we design a new 3-D framework (NbU-5) using the pore space partition strategy: Zn-2(O2CR)(4) paddlewheel units connect tetra-carboxylic linkers to build a primary framework, and 4,4-bipyridine, which acts as a pore-partitioning agent, has been successfully inserted into the cage of the primary framework. Remarkably, NbU-5 exhibits excellent C2H2/CH4 and C2H6/CH4 selectivity, which is proved by breakthrough experiments.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据