期刊
INORGANIC CHEMISTRY
卷 58, 期 9, 页码 5949-5955出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b00271
关键词
-
资金
- National Natural Science Foundation of China [21875146, 21501161, 21702194]
By introduction of K+, Rb+, and Cs+ cations into the classical commercial nonlinear optical crystal LiB3O5 (LBO), the series of novel mixed-alkali-metal borates Li2.6K0.4[B5O8(OH)(2)] (K-LBO), Li2.85Rb0.15[B5O8(OH)(2)] (Rb-LBO), and Li2.9Cs0.1[B5O8(OH)(2)] (Cs-LBO) have been obtained under hydrothermal conditions. The steric hindrance effect generated by the introduction of large alkali-metal cations and partial substitution of small Li+ cations broke the three-dimensional (3-D) framework of [B3O7](5-) borate-oxygen clusters in LBO and resulted in a - structure rearrangement to produce infrequent [B10O26](22-) 2-D layers. The unique layered structure induced an increase in birefringence in A-LBOs (A = K, Rb, Cs), which is favorable for phase matching during second-harmonic generation. All three compounds are potential deep-ultraviolet nonlinear optical materials, which was proved by UV-vis-NIR diffuse reflectance spectroscopy and second-harmonic-generation measurements.
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