期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2019, 期 23, 页码 3744-3750出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201900485
关键词
Diazirines; Spiro compounds; Photoaffinity probes; Heterocycles; Synthesis design
资金
- Enamine Ltd. - Ministry of Education and Science of Ukraine [19BF037-03]
An approach to the synthesis of spirocyclic diazirines from cyclic ketones was examined on a series of carbo- and heterocyclic substrates containing the amine or carboxylic acid moiety. A mini-library of stereochemically diverse functionalized spirocyclic diazirines was synthesized on a multigram scale with 30-81 % yield.
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