期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 101, 期 -, 页码 56-60出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2019.02.010
关键词
Single-droplet; Electrochemical; Fluorescence; Determination; Aluminum
资金
- National Natural Science Foundation of China [21265005]
- Guangxi Natural Science Foundation [2017GXNSFAA198340]
- Project of the High-level Innovation Team and Outstanding Scholars in the Guangxi colleges and universities
- Guangxi College and University Key Laboratory of Food Safety and Detection
- Collaborative Innovation Center for Water Pollution Control and Water Safety in the Karst area
- Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology, the Scientific Research Project of Guangxi Higher Education Institutions [KY2015YB128]
This paper combines a single-droplet-based electrochemical system with an optical fiber fluorescence spectrometer to develop an electrochemical fluorescence method for determining the nanomolar level of aluminum. Al3+ ions were preconcentrated on a glassy carbon rotating disk electrode (RDE) at -2.0 V. After preconcentration, the RDE was rinsed and a droplet (80 mu L) of solution containing 0.2 mM 8-hydroxyquinoline-5-sulfonic acid (HQS) was sandwiched between the RDE (above) and the reference/counter integrated electrode (below). Subsequently, the RDE was rotated and aluminum was stripped into the droplet at -1.4 V; the fluorescence intensity was then measured using a 395 nm LED excitation source. The fluorescence intensity at 515 nm is positively correlated with Al3+ concentration, allowing the determination of aluminum. This method exhibits high selectivity and sensitivity with a detection limit of 7.6 nM. Trace aluminum in real samples was determined by this method and satisfactory results were obtained.
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