期刊
COORDINATION CHEMISTRY REVIEWS
卷 387, 期 -, 页码 1-31出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2019.01.022
关键词
Homogeneous catalysis; C-H functionalization; Metal complex catalysis; Cobalt; Coupling reactions; meta-Chloroperoxybenzoic acid (MCPBA); Peroxides; Stereoselective oxidation
资金
- Russian Foundation for Basic Research [16-03-00254, 16-29-10672]
- Ministry of Science and Higher Education of Russian Federation
Cyclopentadienyl cobalt complexes have been known since 1953. In the recent years, they have attracted attention of chemists due to their application in C-H activation reactions. The review covers the synthesis of cyclopentadienyl cobalt(III) complexes with diverse auxiliary ligands (such as carbonyl, halides, solvents, arenes, amines, phosphines etc.) as well as their catalytic activity. The influence of auxiliary ligands on the catalytic activity is discussed. (C) 2019 Elsevier B.V. All rights reserved.
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