期刊
CONSTRUCTION AND BUILDING MATERIALS
卷 204, 期 -, 页码 684-690出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.conbuildmat.2019.01.232
关键词
Magnesium oxychloride cement; Hydration; Leaching; Microstructure; Modeling; Thermodynamic
资金
- CRSRI Open Research Program [CKWV2018478/KY]
- National Natural Science Foundation of China [51602229, U1507120]
- Jiangsu Province Natural Science Foundation [BK20181187]
- Youth Innovation Promotion Association of Chinese Academy of Sciences [2018467]
- State Key Laboratory of High Performance Civil Engineering Materials [2018CEM011]
- Qinghai Major Science and Technology Project [2014-GX-A2A]
Magnesium oxychloride cement (MOC) has been considered as a kind of eco-friendly cement in view of its significantly low calcination temperature and large capacity of carbon dioxide sequestration, compared with ordinary Portland cement (OPC). In this work, a computer model is established to simulate the hydration and leaching of MOC paste at the micro-scale. The composition of MOC paste in the ultimate hydration is investigated based on the thermodynamic method, and pore structure obtained from the computer simulation is compared with the one from experiments and literature, respectively. The simulated leaching results show that the original solid phase skeleton of MOC paste decomposes into magnesium hydroxide crystals. It is demonstrated that the simulation results are in good agreement with experimental data from literature and the proposed simulation can provide an effective method to reveal the hydration and leaching mechanism of MOC paste. (C) 2019 Elsevier Ltd. All rights reserved.
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