期刊
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
卷 568, 期 -, 页码 445-454出版社
ELSEVIER
DOI: 10.1016/j.colsurfa.2019.02.041
关键词
Silica; Nanoparticles; Dispersity; Precipitation; Surfactant
资金
- National Natural Science Foundation of China [51551201, 51772137]
Disperse ultrafine spherical amorphous SiO2 nanoparticles with high purity are essential for producing SiO2 nanoglass which may show a good toughness. Herein, synthesis of disperse ultrafine spherical amorphous SiO2 nanoparticles with high purity via precipitation and calcination is reported. In the preparation, Na(2)SiO(3.)9H(2)O was used as silicon source, and NH4Cl as a buffer for a catalytic self-condensation of hydroxyl groups during hydrolysis of Na2SiO3 in the alcohol/water solvent system and a slowly hydrolyzed precipitator as well. The main factors affecting the size, dispersity, and shape of amorphous SiO2 nanoparticles including the amount of cetyltrimethyl ammonium bromide (CTAB), different surfactants (sodium dodecyl benzene sulfonate, CTAB, and polyethylene glycol), ethanol/water solvent volume ratio, and different solvent systems were investigated. Welldispersed spherical amorphous SiO2 nanoparticles with an average particle size of 4.0 nm and a size range of 2-12 nm were synthesized using 0.15 g/L CTAB and 1:1 volume ratio of methanol/water and by calcination. The specific surface area of the SiO2 nanoparticles with an average particle size of 4.0 nm is 584 m(2)/g. The SiO2 nanoparticles have a purity of 99.4% (mass percent). The disperse ultrafine spherical amorphous SiO2 nanoparticles have a high purity, the finest particle size, and the largest specific surface area achieved so far.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据