期刊
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
卷 568, 期 -, 页码 356-361出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.colsurfa.2019.02.038
关键词
SiO2 micro/nanofibrous membranes; Surface porous structure; Electrospinning; Freeze drying; Oil sorption capacity
资金
- National Natural Science Foundation of China [51572217, 51672211]
- China Postdoctoral Science Foundation [2015M582689]
- Doctoral Innovation Fund of Xi'an University of Technology [101-liuzhaowei]
Superhydrophobic polymer fibrous membranes have advantages in oil-water separation and oil spill treatment but are not resistant to high temperature and chemical corrosion resistance. Superhydrophobic SiO2 micro/nanofibrous membranes are one of the research hotspots because of the high temperature stability, corrosion resistance, and low cost of SiO2. In this study, camphene was dispersed into the SiO2 spinning solution for freeze electrospinning. SiO2 micro/nanofibrous membranes with porous surface were obtained by camphene sublimation through freeze drying and calcining. The effects of polystyrene and camphene contents on the surface pore structure of SiO2 micro/nanofibrous membranes were investigated. The specific surface area of the porous fibrous membrane was approximately five times as high as that of the conventional electrospun SiO2 micro/nanofibrous membrane. Furthermore, superhydrophobic property was obtained after hexamethyl-disilazane modification. The contact angle of porous fibrous membrane was more than 150 degrees and the sliding angle was just 2.1 degrees. The maximum absorption capacity of the modified SiO2 micro/nanofibrous membrane with porous surface for three kinds of oils can reach 43.7 g/g. In addition, the absorption capacity of the porous membrane for methyl silicone oil was still higher than 34 g/g after repeated use for five times. Hence, porous SiO2 micro/nanofibrous membranes exhibit application prospect in oil/water separation and oil pollution adsorption.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据