期刊
CHEMSUSCHEM
卷 12, 期 14, 页码 3343-3354出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201900925
关键词
catalyst recovery; hydrogenation; levulinic acid; multiphase systems; reductive amination
At 60-150 degrees C and 15-35 bar H-2, two model reactions of levulinic acid (LA), hydrogenation and reductive amination with cyclohexylamine, were explored in a multiphase system composed of an aqueous solution of reactants, a hydrocarbon, and commercial 5 % Ru/C as a heterogeneous catalyst. By tuning the relative volume of the immiscible water/hydrocarbon phases and the concentration of the aqueous solution, a quantitative conversion of LA was achieved with formation of gamma-valerolactone or N-(cyclohexylmethyl)pyrrolidone in >95 and 88 % selectivity, respectively. Additionally, the catalyst could be segregated in the hydrocarbon phase and recycled in an effective semi-continuous protocol. Under such conditions, formic acid additive affected the reactivity of LA through a competitive adsorption on the catalyst surface. This effect was crucial to improve selectivity for the reductive amination process. The comparison of 5 % Ru/C with a series of carbon supports demonstrated that the segregation phenomenon in the hydrocarbon phase, never previously reported, was pH-dependent and effective for samples displaying a moderate surface acidity.
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