期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 25, 期 30, 页码 7243-7258出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201805986
关键词
ab initio calculations; gas-phase reactions; rotational spectroscopy; quantum chemistry; structure elucidation
资金
- NSF [AST-1615847, CHE-1566266, DBI-1555781]
- NASA [NNX13AE59G, 80NSSC18K0396]
- Programme National Physique et Chimie du Milieu Interstellaire (PCMI) of CNRS/INSU
- INC/INP - CEA
- CNES
- Investissements d'Avenir LabEx PALM [ANR-10-LABX-0039-PALM]
Rotational spectroscopy is an invaluable tool to unambiguously determine the molecular structure of a species, and sometimes even to establish its very existence. This article illustrates how experimental and theoretical state-of-the-art tools can be used in tandem to investigate the rotational structure of molecules, with particular emphasis on those that have long remained elusive. The examples of three emblematic species-gauche-butadiene, disilicon carbide, and germanium dicarbide-highlight the close, mutually beneficial interaction between high-level theoretical calculations and sensitive microwave measurements. Prospects to detect other elusive molecules of chemical and astronomical interest are discussed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据