期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 25, 期 35, 页码 8240-8244出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201901397
关键词
amino acids; C-C bond formation; donor-acceptor systems; traceless acceptors; visible light
资金
- Alexander von Humboldt Foundation
- Deutsche Forschungsgemeinschaft [SFB 858]
- Fonds der Chemischen Industrie
The development and application of traceless acceptor groups in photochemical C-C bond formation is described. This strategy was enabled by the photoexcitation of electron donor-acceptor (EDA) complexes with visible light. The traceless acceptors, which were readily prepared from amino acid and peptide feedstocks, could be used to alkylate a wide range of heteroarene and enamine donors under metal- and peroxide-free conditions. The crucial role of the EDA complexes in the mechanism of these reactions was explored through combined experimental and computational studies.
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