期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 25, 期 22, 页码 5719-5732出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201806304
关键词
ambipolar; charge transfer; coordination chemistry; liquid crystals; platinum
资金
- CNRS
- Rennes Metropole
- University of Rennes 1
- GENCI [2018-A0040805032]
Platinum diimine dithiolene complexes bearing mesogenic groups on one or both ligands have been prepared through an original ligand metathesis reaction to introduce the dithiolene ligand. The neutral diimine ligands, the intermediate platinum dichloride diimine complexes, and the target compounds were characterized by a combination of electronic (electrochemistry, absorption and emission spectroscopy, DFT calculations) and structural (SAXS, DSC) tools. Several novel liquid crystalline platinum diimine-dithiolene were identified over a large temperature range, and the systems were endowed with ambipolar properties, associated with the high reversibility of both oxidation and reduction processes.
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