期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 25, 期 40, 页码 9405-9409出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201900807
关键词
gold catalysis; gold-carbene; oxa-bridged bicycle; rearrangement reaction
资金
- Ministry of Science and Technology of the People's Republic of China [2016YFA0602900]
- NSFC [21871096, 21672071]
- Guang-dong Science and Technology Department [2018B030308007, 2018A030310359, 2016A030310433]
- Science and Technology Program of Guangzhou [201707010316]
- China Postdoctoral Science Foundation [2018M633042]
A gold (I)-catalyzed reaction of enyne-ethers to rapidly construct oxa-bridged compounds via a tandem 1,2-acyloxy migration/intramolecular oxonium formation/1,2-rearrangement process was reported. The reaction was shown to be robust with a wide range of substitution patterns tolerated to provide the corresponding oxygen-containing bridged products in good to excellent yields.
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