期刊
CERAMICS INTERNATIONAL
卷 45, 期 14, 页码 16940-16947出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2019.05.242
关键词
P-V-L theory; Vibrational spectra; NdNbO4; Microwave dielectric ceramics
资金
- National Natural Science Foundation of China [51872037]
- National Synchrotron Radiation Laboratory (NSRL) [BL01B]
Coordination chemistry, bond state and vibrational spectrum of co-substituted microwave dielectric NdNb1-x(Zr0.5W0.5)(x)O-4 ceramics (x = 0.01 similar to 0.05) were investigated. Raman spectra and XRD refinement showed a solid solution was formed. The compressed and elongated chemical bonds are responsible for the variations of crystal parameters and cell volume. Calculated chemical bond parameters indicated bond covalency, lattice energy and Nb-site bond energy act on the fluctuations of the permittivity, quality factor and temperature coefficient, respectively. Meanwhile, the infrared vibrational spectrum is fitted to quantify the contributions of observed IR mode to the intrinsic loss. Compact ceramic possesses excellent properties: epsilon(r) similar to 19.2, Q x f similar to 55282 GHz and tau(f) similar to -11.36 ppm/degrees C with x = 0.04, at 1250 degrees C.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据