期刊
CERAMICS INTERNATIONAL
卷 45, 期 7, 页码 8406-8413出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2019.01.149
关键词
NiCo2O4; Surfactant aggregates; Firework-shaped microspheres; Necklace-like structure; Supercapacitors
资金
- National Natural Science Foundation of China [51572134, 51372124, 51503108]
- Program for Scientific Research Innovation Team in Colleges and Universities of Shandong Province
NiCo2O4 nanorods and firework-shaped microspheres formed with necklace-like structures were prepared through a facile hydrothermal method by using cetyltrimethylammonium bromide (CTAB) and sodium dodecyl sulfate (SDS) aggregates as soft templates. The morphologies of NiCo2O4 were manipulated by adjusting the amount of beta-cyclodextrin (beta-CD) added to the mixture of CTAB and SDS. Necklace-like NiCo2O4 nanorods composed of numerous nanospheres were obtained under low beta-CD content. Under high beta-CD content, NiCo2O4 transformed into firework-shaped microspheres through the self-assembly of necklace-like NiCo2O4 nanorods. NiCo2O4 reverted to nanorods as beta-CD content further increased. The two morphologies of NiCo2O4 were characterized in 2 M KOH electrolyte solution with a three-electrode system. At the current density of 1 A g(-1), the specific capacitance of firework-shaped NiCo2O4 microspheres reach the high value of 697.5 F g(-1) and is higher than that of NiCo2O4 nanorods (525 F g(-1)) In addition, the firework-shaped NiCo2O4 microspheres demonstrate excellent long-term cycle stability with 85.77% capacitance retention after 10,000 cycles at the current density of 1 A g(-1). These findings imply that the firework-shaped NiCo2O4 microspheres obtained by adjusting the beta-CD content of CTAB and SDS aggregates have considerable application potential as electrode materials for supercapacitors.
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