期刊
CERAMICS INTERNATIONAL
卷 45, 期 12, 页码 15660-15670出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2019.05.078
关键词
Silica; Zirconia; Zircon; Structural characteristics
资金
- Ministry of Research Technology and Higher Education of the Republic of Indonesia
- Institute for Research and Community Services ITS under the PMDSU program [821/PKS/ITS/2018]
The structural characteristics of polymorphic raw material combinations of silica-zircogia powder systems were investigated through X-ray diffraction (XRD), Wide-angle X-ray scattering (WAXS), Fourier transform infrared (FTIR), and X-ray absorption near edge structure (XANES). Stoichiometric mixtures (1:1 mol% ratio) of silica (SiO2: amorphous and cristobalite) and zirconia (ZrO2: amorphous and tetragonal zirconia) were prepared with the addition of polyvinyl alcohol (PVA) and a ball-mill mechanical activation of 5 h, followed by calcination at 1000 and 1200 degrees C. The identified phases of the calcined powders were a combination of zircon, zirconia, and cristobalite. Quantitative phase analyses of the XRD and WAXS data based on the Rietveld method revealed that the amorphous-amorphous (AA) mixture contained a higher zircon composition than the others, ca 93 mol%, at a calcination temperature as low as 1000 degrees C. Rietveld analysis of the WAXS data was in good agreement with that of the XRD data. The PVA and ball-mill mechanical activation simultaneously enhanced the solid-state reaction. The peaks of IR absorption associated with zircon were observed at wavenumbers around 435, 615, and 900 cm(-1). The IR absorption peak observed at around 1000 cm(-1) indicated silica-rich content in the AT1000 and CA1000 samples. A Si K-edge XANES analysis indicated a structural distortion around Si in the zircon containing samples as compared to the silica, resulting in an extra lower-energy peak. The ratio between the absorption intensities of the extra and the highest peaks, in general, confirmed the phase composition of zircon in the samples.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据